Binary Systems Research Articles

Forming off-center massive black hole binaries in dwarf galaxies through Jacobi capture

It is well established that black holes reside in the central regions of virtually all types of known galaxies. Recent observational and numerical studies however challenge this picture, suggesting that intermediate-mass black holes in dwarf galaxies may be found on orbits far from the center. In particular, constant-density cores minimize orbital energy losses due to dynamical friction, and allow black holes to settle on stable off-center orbits. Using controlled simulations, we study the dynamics of off-center black holes in dwarf galaxies with such cores. We propose a new scenario to describe off-center mergers of massive black holes, starting with a Jacobi capture. We focus on initially circular and co-planar black hole orbits and explore a large parameter space of black hole masses and orbital parameters. We find that Jacobi captures are a complex and chaotic phenomenon that occurs in about $13<!PCT!>$ of cases in this simplified setup, and we quantify how the likelihood of capture depends on the simulation parameters. We note that this percentage is likely an upper limit of the general case. Nevertheless, we show that Jacobi captures in cored dwarf galaxies can facilitate the formation of off-center black hole binaries, and that this process is sufficiently common to have a substantial effect on black hole growth. While our setup only allows for temporary captures, we expect dissipative forces from baryons and post-Newtonian corrections to maintain the captures over time and to lead to the formation of stable binary systems. This motivates future studies of the effectiveness of such dissipative forces, within stripped nuclei or globular clusters, in forming stable bound systems.

A comprehensive study on crystal structure, phase compositions of the BiVO4-LaVO4 binary dielectric ceramic system and a typical design of dielectric resonator antenna for C-band applications

Novel multi-component (Bi1-xLax)VO4 (BLVOx) (0.05 ≤ x ≤ 0.9) solid-solution/composite ceramics crystal structures, phase compositions as well as its applications in the C-band dielectric resonator antenna have been designed and investigated. With the increased substitution of La3+, phase transitions among the monoclinic scheelite (mBiVO4), tetragonal zircon (zt(La,Bi)VO4) and monoclinic monazite (mLaVO4), driven by the compositional changes, were detected. La3+ played an essential role in the optimization of the dielectric properties of BLVOx. The measured Q × f values at the microwave band are considerably larger around the range of compositions forming the zircon phase and reached the maximum value (12,800 GHz) at pure zircon phase (x = 0.5), demonstrating that the impact of zircon structure on the intrinsic loss should not be disregarded and is beneficial for low dielectric loss. Meanwhile, the εr and TCF values could be tuned by regulating the concentration ratio of Bi3+/La3+ to obtain composites or solid-solutions with appropriate εr and near-zero TCF values. Additionally, a cylindrical dielectric resonator antenna (CDRA) of BVLO0.5 ceramic was designed with high simulated radiation efficiency (99.8%) and gain (4.58 dBi) at the center frequency (6.73 GHz), indicating its potential application in C-band because of its tunable permittivity and low-loss.

Re-investigation of the Phase Equilibria and Thermodynamic Assessment of the Mg-Sm Binary System

Re-investigation of the Phase Equilibria and Thermodynamic Assessment of the Mg-Sm Binary System

Computer Simulation of Three-Phase Equilibria for Some Water/n-Alkane Binary Systems.

In this work, the vapor-liquid-liquid equilibrium (VLLE) of the water/n-pentane, water/n-hexane, water/n-octane, and water/n-decane binary systems is calculated by computer simulation using the NVT-Gibbs ensemble (in the version of three simulation boxes) combined with the configurational bias Monte Carlo method. The combination of both methods, the molecular potential models used, and the simulation details allowed us to calculate the triphasic equilibrium properties of the systems studied: the densities of the three phases in equilibrium, their compositions, and potential energies. In previous works, these simulations were not carried out at a temperature range nor water/n-alkanes systems simulated in this work, probably because they are highly nonideal systems; so, to the best of our knowledge, this is the first time that this phenomenon is studied in detail. The results from VLLE simulations of the water/n-pentane system for temperatures from 343.2 to 435 K, the water/n-hexane system for temperatures from 373.11 to 473.15 K, the water/n-octane system for temperatures from 310.9 to 500 K, and for the water/n-decane system for temperatures from 374.15 to 525 K are reported here. The temperature range was selected in concordance with the experimental data available for an adequate study of the VLLE simulation results. The subcritical densities (vapor and liquid rich in n-alkane phases) at various temperatures fit well with the scaling law and the law of rectilinear diameters, allowing the estimation of upper critical end point temperature and density of the VLLE. The simulation results show a good prediction with experimental data reports in the literature.

Prospects for the observation of continuous gravitational waves from deformed fast-spinning white dwarfs

Abstract There has been a growing interest within the astrophysics community in highly magnetized and fast-spinning white dwarfs (WDs), commonly referred to as HMWDs. WDs with these characteristics are quite uncommon and possess magnetic fields ≥106 G, along with short rotation periods ranging from seconds to just a few minutes. Based on our previous work, we analyze the emission of Gravitational Waves (GWs) in HMWDs through two mechanisms: matter accretion and magnetic deformation, which arise due to the asymmetry surrounding the star’s rotational axis. Here, we perform a thorough self-consistent analysis, accounting for rotation and employing a realistic equation of state to investigate the stability of stars. Our investigation focuses on the emission of gravitational radiation from six rapidly spinning WDs: five of them are situated within binary systems, while one is an AXP, proposed as a magnetic accreting WD. Furthermore, we apply the matter accretion mechanism alongside the magnetic deformation mechanism to assess the influence of one process on the other. Our discoveries indicate that these WDs could potentially act as GW sources for BBO and DECIGO, depending on specific parameters, such as their mass, the angle (α) between the magnetic and rotational axes, and the accumulated mass (δm) at their magnetic poles, which is influenced by the effect of matter accretion. However, detecting this particular class of stars using the LISA and TianQin space detectors seems unlikely due to the challenging combination of parameters such as a large δm, a large α angle and a small WD mass value.

Dynamic Studies of Binary Adsorption System in Fixed Beds using Orthogonal Collocation on Finite Element Method

Dynamic Studies of Binary Adsorption System in Fixed Beds using Orthogonal Collocation on Finite Element Method

Three-Body Binary Formation in Clusters: Analytical Theory

Abstract Binary formation in clusters through triple encounters between three unbound stars, ‘three-body’ binary formation, is one of the main dynamical formation processes of binary systems in dense environments. In this paper, we use an analytical probabilistic approach to study the process for the equal mass case and calculate a probability distribution for the orbital parameters of three-body-formed binaries, as well as their formation rate. For the first time, we give closed-form analytical expressions to the full orbital parameter distribution, accounting for both energy and angular momentum conservation. This calculation relies on the sensitive dependence of the outcomes of three-body scatterings on the initial conditions: here we compute the rate of three-body binaries from ergodic interactions, which allow for an analytical derivation of the distribution of orbital parameters of the binaries thus created. We find that soft binaries are highly favoured in this process and that these binaries have a super-thermal eccentricity distribution, while the few hard three-body binaries have an eccentricity distribution much closer to thermal. The analytical results predict and reproduce simulation results of three-body scattering experiments in the literature well.

Binary mergers in strong gravity background of Kerr black hole

Abstract Binary-black-hole (BBH) mergers can take place close to a supermassive black hole (SMBH) while being in a bound orbit around the SMBH. In this paper, we study such bound triple systems and show that including the strong gravity effects of describing the SMBH with a Kerr metric can significantly modify the dynamics, as compared to a Newtonian point particle description of the SMBH. We extract the dynamics of the system, using a quadrupole approximation to the tidal forces due to the SMBH. We exhibit how the gyroscope precession is built into this dynamics, and find the secular Hamiltonian by both averaging over the inner and outer orbits, the latter being the orbit of the BBH around the SMBH. We study the long-time-scale dynamics, including the periastron precession and GW radiation-reaction of the binary system, finding that the strong gravity effects of the SMBH can enhance the von Zeipel-Lidov-Kozai mechanism, resulting in more cycles, higher maximum eccentricity, and thereby a shorter merger time, particularly when the binary is close to, or at, the innermost stable orbit of the SMBH. We end with an analysis of the peak frequency of the GW emission from the binary system, highlighting possible observable signatures in the ET and LISA frequency bands.

Constraints on Neutrino Natal Kicks from Black-Hole Binary VFTS 243

The recently reported observation of VFTS 243 is the first example of a massive black-hole binary system with negligible binary interaction following black-hole formation. The black-hole mass (≈10M⊙) and near-circular orbit (e≈0.02) of VFTS 243 suggest that the progenitor star experienced complete collapse, with energy-momentum being lost predominantly through neutrinos. VFTS 243 enables us to constrain the natal kick and neutrino-emission asymmetry during black-hole formation. At 68% confidence level, the natal kick velocity (mass decrement) is ≲10 km/s (≲1.0M⊙), with a full probability distribution that peaks when ≈0.3M⊙ were ejected, presumably in neutrinos, and the black hole experienced a natal kick of 4 km/s. The neutrino-emission asymmetry is ≲4%, with best fit values of ∼0–0.2%. Such a small neutrino natal kick accompanying black-hole formation is in agreement with theoretical predictions. Published by the American Physical Society 2024

Host–Guest Interaction Study of Olmesartan Medoxomil with β-Cyclodextrin Derivatives

Olmesartan medoxomil (OLM) is a selective angiotensin II receptor antagonist used in the treatment of hypertension. Its therapeutic potential is limited by its poor water solubility, leading to poor bioavailability. Encapsulation of the drug substance by two methylated cyclodextrins, namely randomly methylated β-cyclodextrin (RM-β-CD) and heptakis(2,3,6-tri-O-methyl)-β-cyclodextrin (TM-β-CD), was carried out to overcome the limitation related to OLM solubility, which, in turn, is expected to result in an improved biopharmaceutical profile. Supramolecular entities were evaluated by means of thermoanalytical techniques (TG—thermogravimetry; DTG—derivative thermogravimetry), spectroscopic methods including powder X-ray diffractometry (PXRD), universal-attenuated total reflectance Fourier-transform infrared (UATR-FTIR) and UV spectroscopy, saturation solubility studies, and by a theoretical approach using molecular modeling. The phase solubility method reveals an AL-type diagram for both inclusion complexes, indicating a stoichiometry ratio of 1:1. The values of the apparent stability constant indicate the higher stability of the host–guest system OLM/RM-β-CD. The physicochemical properties of the binary systems are different from those of the parent compounds, emphasizing the formation of inclusion complexes between the drug and CDs when the kneading method was used. The molecular encapsulation of OLM in RM-β-CD led to an increase in drug solubility, thus the supramolecular adduct can be the subject of further research to design a new pharmaceutical formulation containing OLM, with improved bioavailability.

H.E.S.S. observations of the 2021 periastron passage of PSR B1259-63/LS 2883

is a gamma-ray binary system that hosts a pulsar in an eccentric orbit, with a 3.4 year period, around an O9.5Ve star (LS 2883). At orbital phases close to periastron passages, the system radiates bright and variable non-thermal emission, for which the temporal and spectral properties of this emission are, for now, poorly understood. In this regard, very high-energy (VHE) emission is especially useful to study and constrain radiation processes and particle acceleration in the system. We report on an extensive VHE observation campaign conducted with the High Energy Stereoscopic System, comprised of approximately 100 hours of data taken over five months, from p -24$ days to $t_ p +127$ days around the system's 2021 periastron passage (where $t_ p $ is the time of periastron). We also present the timing and spectral analyses of the source. The VHE light curve in 2021 is consistent overall with the stacked light curve of all previous observations. Within the light curve, we report a VHE maximum at times coincident with the third X-ray peak first detected in the 2021 X-ray light curve. In the light curve -- although sparsely sampled in this time period -- we see no VHE enhancement during the second disc crossing. In addition, we see no correspondence to the 2021 GeV flare in the VHE light curve. The VHE spectrum obtained from the analysis of the 2021 dataset is best described by a power law of spectral index $ stat sys $, a value consistent with the spectral index obtained from the analysis of data collected with H.E.S.S. during the previous observations of the source. We report spectral variability with a difference of $ stat sys $ at $95 <!PCT!>$ confidence intervals, between sub-periods of the 2021 dataset. We also detail our investigation into X-ray/TeV and GeV/TeV flux correlations in the 2021 periastron passage. We find a linear correlation between contemporaneous flux values of X-ray and TeV datasets, detected mainly after $t_ p +25$ days, suggesting a change in the available energy for non-thermal radiation processes. We detect no significant correlation between GeV and TeV flux points, within the uncertainties of the measurements, from $ t_p-23$ days to $ t_p+126$ days. This suggests that the GeV and TeV emission originate from different electron populations.

A Sustainable Approach for Enhancing Cationic Dyes Adsorption in Single and Multiple Systems using Novel Nano Ferrites Modified with Walnut Shell

AbstractWalnut shell has been used in various experimental studies for different dyes removal, but it is exciting to study the adsorption behaviour of bio‐waste (walnut shell) in combination with spinel zinc ferrite which resulted in the formation of a novel material having magnetic properties and help in easy separation after the wastewater treatment. Novel magnetic walnut shell zinc ferrite (WSZF) composite has been synthesized and used to remove Malachite Green and Methylene Blue from aqueous solution in single and binary dye systems. Different techniques have been used to characterize the composite such as Fourier Transform Infrared Spectroscopy, X‐Ray Diffraction, Field Emission Scanning Electron Microscopy, Energy Dispersive Spectroscopy, Thermogravimetric Analysis and pHzpc. Adsorption of dyes were studied to see the effect of time, pH, adsorbent dose, dye concentration and temperature. The Lagergren pseudo second order model fitted well among various kinetic models employed. Langmuir adsorption isotherm best fitted with maximum adsorption capacities of 86.20 and 169.5 mg/g in single dye and 23.92 and 18 mg/g respectively in binary dye system for Malachite Green and Methylene Blue. Process was spontaneous and ΔH° were found positive, confirmed endothermic process of adsorption. The composite‘s regeneration capacity was studied for five cycles and at the end of five cycle the efficiency of the material was found to be around 80 % for both single as well as binary dye systems. It is concluded that the chosen WSZF will be the optimum solution for cationic dyes removal.

Doppler Tomography of the Circumstellar Disk of the Be Star κ Draconis

κ Draconis is a binary system with a classical Be star as the primary component. Its emission-line spectrum consists of hydrogen lines, notably the Hα line with peak intensity ratio (V/R) variations phase-locked with the orbital period P = 61.55 days. Among binaries demonstrating the Be phenomenon, κ Dra stands out as one of a few systems with a discernible mass of its secondary component. Based on more than 200 spectra obtained in 2014–2023, we verified the physical parameters and constructed the mass function. We used part of these data obtained in 2014–2021 to investigate regions in the circumstellar disk of the primary component that emit the Hα line using the Doppler tomography method. The results show that the disk has a non-uniform density distribution with a prominent enhancement at Vy ≈ 99 km s−1 and Vx≈−6 km s−1 that corresponds to a cloud-like source of the double-peaked Hα line profile. We argue that this enhancement’s motion is responsible for the periodic variations in the Hα V/R ratio, which is synchronised in orbital phase with the radial velocity (RV) of absorption lines from the atmosphere of the primary component.

Characterization Electrospun Nanofibers Based on Cellulose Triacetate Synthesized from Licorice Root Cellulose

Cellulose triacetate (CTA) nanofibers were formed by electrospinning using two binary solvent systems: methylene chloride/ethanol and chloroform/acetone. Previously, licorice root cellulose (LRC) with a degree of polymerization (DP) of 710 was extracted from licorice root waste by alkaline treatment and hydrogen peroxide bleaching at high temperatures. Then CTA with a degree of substitution (DS) of 2.9 and an average molecular weight of 175 kDa was synthesized from LRC using acetic acid and acetic anhydride, sulfuric acid was as a catalyst. The influence of the electrospinning process and various solvent systems on the morphology and structure of nanofibers is studied. The structure and morphology of the nanofibers were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction, scanning electron microscopy (SEM), thermal gravimetric analysis (TGA), and the sorption characteristics were also investigated. The results showed that the morphology and structure of nanofibers depended on the solvent mixture used. The average diameters of the CTA nanofibers with grooved morphology varied 200-700 nm (solvent methylene chloride/ethanol) and the dumbbell-shaped (flat ribbon) CTA nanofibers in a wide range from 200 nm to 4 mkm (solvent chloroform/acetone).

UNIFAC PREDICTION OF VAPOR LIQUID EQUILIBRIA INVOLVING GAMMA-VALEROLACTONE DERIVATIVE SYSTEMS

Researchers have studied the hydrogenation of Gamma-Valerolactone (GVL) over Ru/C to produce 2-methyltetrahydrofuran (2-MTHF), a biomass-based platform chemical with potential as a biofuel and green solvent. Other byproducts of this reaction include 2-butanol (2-BuOH), 2-pentanol (2-PeOH), and 1,4-pentanediol (1,4-PDO). In this study, UNIFAC activity coefficient models were used to predict the vapor-liquid equilibrium of several systems included in the process to explain the phase behavior which is important in purification process. The accuracy of the UNIFAC model is tested by comparing the experimental boiling points for the binary system of 2-propanol + 1-butanol and the vapor-liquid equi-librium of the GVL + 2-MTHF system. From this comparison, the Root Mean Square Deviation (RMSD) values for the boiling point measurements are obtained to be 3.153%, and for the liquid and vapor phases in the vapor-liquid equilibrium measurements, the RMSD values are 1.934% and 0.298% respectively. These RMSD values indicate the level of accuracy of the UNIFAC model in representing the experimental data for both boiling point measurements and vapor-liquid equilibrium phase behavior. The prediction results of vapor-liquid equilibrium data for GVL derivative systems showed that the 2-BuOH + 2-MTHF system does form an azeotrope when the mol fraction of 2-BuOH is 0.0031 at 79.780C. The calculation was performed using ChemCAD commercial software for chemical process modeling and simulation

Study of Activation Energy for Viscous Flow of Mixtures as a Measure of Dilution Efficiency for Heavy Oil-Diluent Systems

Study of Activation Energy for Viscous Flow of Mixtures as a Measure of Dilution Efficiency for Heavy Oil-Diluent Systems

Theoretical Investigation of Mechanical and Electronic Properties of Hexagonal BaB2

A comprehensive investigation of the electronic and mechanical properties in the hexagonal BaB2 binary system using state of the art first-principles computational techniques is critical for an in-depth understanding of the fundamental properties unique to this binary system. In this context, we derived elastic constants using the metric-tensor formulation, which allowed us to find important mechanical properties such as Bulk Modulus, Shear Modulus, and Vickers's hardness which are fundamental mechanical quantities. Also, this research includes a detailed analysis of the electronic band structures and a study comparison of Fermi surface topologies. The charge density at the Fermi level (N(EF)), which is very important in superconductivity theories, was found to be 1.43 states/eV.uc. Furthermore, we have explored whether there exists a close relationship between these properties and the superconducting behavior of the BaB2 material. Nevertheless, our calculations unequivocally demonstrate that the information derived from electronic band structures and Fermi surfaces alone is insufficient for a comprehensive explanation of the superconductivity phenomenon observed in such materials.

Calculations of solubilities of pure noble gases and He–CO2/CH4/N2 gas mixtures in aqueous solutions with accurate thermodynamic models

Determining solubilities of pure noble gases and He–CO2/CH4/N2 gas mixtures in aqueous solutions is essential for various applications of noble gases in geological processes and for understanding the migration and accumulation of helium. This study developed two thermodynamic models for calculations of solubilities of five pure noble gases (i.e. He, Ne, Ar, Kr, and Xe) and He–CO2/CH4/N2 gas mixtures in water and in aqueous NaCl solution. The first model is constructed by extending the improved SAFT-LJ equation of state (EOS) to five binary H2O-noble gas systems and four ternary systems (i.e. H2O–He–NaCl, H2O–He–CO2, H2O–He–CH4, and H2O–He–N2). Both the non-ideality of aqueous phase and that of vapor phase of these systems were described using the improved SAFT-LJ EOS (φ-φ model). The second model is developed by modifying the gas solubility model proposed by Duan and his coworkers (one type of γ-φ model). The Pitzer theory was used to describe the non-ideality of aqueous phase and the improved SAFT-LJ EOS was used to describe the non-ideality of vapor phase. Both binary adjustable parameters of the improved SAFT-LJ EOS and parameters of the modified solubility model for pure gas were evaluated from experimental solubility data for pure gas. Both models are predictive for solubilities of gas mixtures since there is no need to evaluate their parameters from solubility data of gas mixtures.Comparisons of calculations of two models with experimental data show that both models can well represent solubilities and Henry's coefficients of five noble gases in pure water, as well as the solubility of He in aqueous NaCl solutions over a wide P-T range (273–600 K, 1–2000 bar for the solubility of He in water). The absolute average deviation of the improved SAFT-LJ EOS from experimental solubility data for five noble gases in pure water is 3.14% and that of the modified solubility model is 2.21%. Predictions of the improved SAFT-LJ EOS for Henry's coefficients for He in the He–CO2–H2O system are consistent with available experimental data. According to predictions of the improved SAFT-LJ EOS, Henry's coefficient for He in the He–CO2–H2O system is always lower than that in the He–H2O system at the same depth. Within 0–5 km depth, He solubility of He–CO2 gas mixture is much greater than that of pure He at the same depth and He partial pressure, He solubility of He–N2 mixture is a little greater than that of pure He, and He solubility of He–CH4 mixture is between that of He–CO2 mixture and that of He–N2 mixture. A computer program for calculations of solubilities of pure noble gases and He–CO2/CH4/N2 gas mixtures in pure water and in aqueous NaCl solutions can be obtained from the corresponding author via email.

Spontaneous Liquefaction of Solid Metal-Liquid Metal Interfaces in Colloidal Binary Alloys.

Crystallization of alloys from a molten state is a fundamental process underpinning metallurgy. Here the direct imaging of an intermetallic precipitation reaction at equilibrium in a liquid-metal environment is demonstrated. It is shown that the outer layers of a solidified intermetallic are surprisingly unstable to the depths of several nanometers, fluctuating between a crystalline and a liquid state. This effect, referred to herein as crystal interface liquefaction, is observed at remarkably low temperatures and results in highly unstable crystal interfaces at temperatures exceeding 200 K below the bulk melting point of the solid. In general, any liquefaction process would occur at or close to the formal melting point of a solid, thus differentiating the observed liquefaction phenomenon from other processes such as surface pre-melting or conventional bulk melting. Crystal interface liquefaction is observed in a variety of binary alloy systems and as such, the findings may impact the understanding of crystallization and solidification processes in metallic systems and alloys more generally.

Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the Latest Experimental Phase Diagram

Thermodynamic Evaluation of the Fe-Zn Binary System with Reference to the Latest Experimental Phase Diagram